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July 9th, 2008, 11:36 GMT · By Gabriel Gache

How Breathalyzers Work

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Image of an Alcohawk breathalyzer
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I'm going to make this easy and simply say that a breathalyzer is a drunk driver's worst nightmare. You might have seen one on television, used on a person or even on you, but how does it work? A breathalyzer is a simple device used by law enforcements to determine whether or not a person driving a certain vehicle is intoxicated and if the alcohol concentration in the suspect's blood falls within legal limits.

The principle on which most breathalyzers work actually involves measuring the concentration of alcohol in the air exhaled by the suspect, from which the device extrapolates the concentration of alcohol in the bloodstream. Since alcohol is not immediately digested, it may remain in the bloodstream for up to several hours after it's been ingested. Part of the blood then passes in the lungs, where traces of alcohol will eventually be released along with the exhaled air and instantly detected by the breathalyzer.

The ratio of alcohol concentration in the exhaled air in relation to the concentration in the blood is about 2,100:1, meaning that 2,100 milliliters of exhaled air will contain an identical amount of alcohol as 1 milliliter of blood. It's worth mentioning that the standard upper limit above which a driver is considered drunk is 0.08, or 0.08 grams of alcohol per 100 milliliters of blood.

There are several types of breathalyzers currently used throughout the world, amongst which the Breathalyzer, Intoxilyzer and the Alcosensor, all of which rely on measuring the alcohol concentrations in the exhaled air.

The Breathalyzer, is a simple device consisting of a sampling system, a reaction chamber and a detector. Part of the air that the suspect blows through the sampling system is redirected to the reaction chamber containing several chemicals that have the role of retaining and reacting with any trace of alcohol in the air.

When alcohol reacts with the compounds in the reaction chamber, it changes their color according to the concentration of alcohol in the air. This change in color is then measured with the help of a photocell system and displayed on a scale.

The Intoxilyzer, makes use of the optical properties of alcohol in the infrared spectrum. As air is being blown through a sampling chamber, an infrared beam is projected through the mass of air. The intensity of the beam is measured by a photocell for variations, after which it relays the obtained values to a microprocessor, which then calculates the concentration of alcohol in the blood.

Another type of widely used breathalyzer is the Alcosensor, which relies on a fuel-cell made out of two platinum electrodes separated by acid-electrolyte porous material. When air containing concentrations of alcohol flows from one side to the other, acetic acid is being produced along with positive ions and electrons. The first electrode collects the electrons, while the positive ions move to the other side of the cell where they combine with oxygen.

The electrical current established between the two electrodes represents an accurate test in revealing the concentration of alcohol in the exhaled air.
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breathalyzer
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alcohol
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Comment #1 by: breathtester on 08 Dec 2009, 04:27 UTC reply to this comment

This article is very misleading as it mixes brand names with different breathalyzer technologies.

There are a few primary types of breath analyzer devices for determining blood alcohol levels in the body, each based on a different technology:

* Infrared testers detect alcohol in a breath sample by using infrared spectroscopy. This technology works by identifying how molecules absorb infrared light. Each type of bond within a molecule absorbs infrared light at different wavelengths, so in order to determine if there is ethanol (alcohol) in a breath sample, the amount of infrared absorption is measured.
This technology is found in breathalyzers used by Police almost exclusively.

* Fuel cell technology uses fuel cells to detect chemical reactions of alcohol. These fuel cells have two platinum electrodes on either side of a porous, acid-electrolyte material. As the air flows past one side of the fuel cell, the platinum oxidizes any alcohol that’s in the air and produces acetic acid, protons and electrons. The electrical current that is established between the two electrodes can reveal the presence of alcohol in the air sample. this technology is used by Law Enforcement breathalyzers and in quality consumer units.


* Semiconductor devices also use a current to determine the presence of alcohol. A small, charged bead of tin oxide is headed to 300 degrees Celsius. When alcohol comes into contact with the bead, the current changes. The degree of change determines the concentration of alcohol in the breath. This technology is used in the inexpensive novelty testers sold in many mass merchant stores. It is neither accurate nor consistent from test to test. It should not be relied upon by serious users.


Comment #2 by: Lindy on 26 Apr 2010, 05:35 UTC reply to this comment

Another aspect, not discussed, is that a person could have fresh/recent alcohol in their mouths, and get a positive reading, whereas, there could be little or NO alcohol yet in their blood. I recent purchased a very cheal breathalyzer on eBay, and have been playing around with it.... Swishing Listerine in my mouth gave a full-blown positive reading..... I seldom drink, maybe a glass of wine with friends, but I really prefer tea or coffee.... I have had no alcohol of any type for well over a week....
So I'm thinking that many people should insist upon a blood test, as these breathalyzers are going to give false-positives after a recent drink, or after Listerine, and perhaps other things.


Comment #3 by: Wrong Solution on 24 Feb 2011, 19:35 UTC reply to this comment

How do these systems account for differences in lung capacity and air volume blown through them? i.e., if someone has great cardiovascular health and blows a higher volume of air than say a chronic smoker, would the system show a higher BAC just because more air sample is being pushed through and thus provide a false BAC?


Comment #4 by: Pissedoff@chemproject on 22 Dec 2011, 02:53 UTC reply to this comment

This information is good, however I would like to know more about the disadvantages of these devices. In that field, are they the same as a breathalyzer?

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